If you're charging LFP batteries, then they are likely internally imbalanced, i.e., ONE cell is hitting max, and it's cutting the battery out of the charge circuit instantly. The MPPT spikes the voltage because it can't shut itself off fast enough.
The solution for this is to reduce absorption voltage to reduce/eliminate spikes and increase balance time.
In this case, 3.45V/cell absorption and 3.40V/cell float
absorption/float
12V: 13.8/13.6V
24V: 27.6/27.2V
48V: 55.2/54.4V
You'll want to increase your absorption period to 2-4 hours if possible.