Active balancer, make it smart!?

[Hans Kroeger]

Many thanks for this chart!
If i read this chart correctly then even at 0.04C i could charge it till 3.65V without overcharging it. Since i stay below 3.65V my cells should be fine.

Correct, if you turn off the charger at 3,65 V AND at 0.04C Amps.

Also another takeaway is (if i understood correctly) if i would charge CC with say 0.01C i could overcharge the cells given i do this long enough. If i would charge CC till 3.45V with 0.5C and then switch to CV and stop at 0.1C i could never overcharge them but would come close to if not hit 100%soc.

I am not clear about that statement. The important information of that curve is the red line:
If you charge with CC up to the point where the charger goes to CV, the red line tells you for that particular voltage at which current level you must turn off the charger, in order not to overcharge the cell.
e.g.: If you charge a 100 Ah cell with 0.2 C (=20 A) in CC mode up to CV = 3.65 V then you must wait in CV mode at 3.65 V until the current tapers off to 0.033 ...0.05 C (3.3 ...5 A for a 100 Ah cell). Then you must stop charging (or reduce the Voltage to 3.37 V maximum) in order not to overcharge the cell.
Note: All chargers with a floating voltage of more than 3.37 V per cell will cause a reduced life time .....

 

[Vi s]

Correct, if you turn off the charger at 3,65 V AND at 0.04C Amps.

I am not clear about that statement. The important information of that curve is the red line:
If you charge with CC up to the point where the charger goes to CV, the red line tells you for that particular voltage at which current level you must turn off the charger, in order not to overcharge the cell.
e.g.: If you charge a 100 Ah cell with 0.2 C (=20 A) in CC mode up to CV = 3.65 V then you must wait in CV mode at 3.65 V until the current tapers off to 0.033 ...0.05 C (3.3 ...5 A for a 100 Ah cell). Then you must stop charging (or reduce the Voltage to 3.37 V maximum) in order not to overcharge the cell.
Note: All chargers with a floating voltage of more than 3.37 V per cell will cause a reduced life time .....

Let's say i charge with 0.5C. according to that chart i can charge even above 3.65V and i am still not overcharging the cell (still in the green). Can this be right? What is the voltage at 0.5C at which the cell is overcharged? Overcharging means charging a cell beyond its designed capacity right!? So why does the voltage (pressure) rise? Since voltage and capacity are not linear it can't be only because the cell gets closer and closer to full capacity or?

 

[Hans Kroeger]

Where is this from?

Sorry, I don't remember. But you find similar presentations in scientific papers dealing with that subject.

 

[Horsefly]

Sorry, I don't remember. But you find similar presentations in scientific papers dealing with that subject.

When you didn't answer I used Google to find it. It was the (somewhat) famous Nordkyn Design site. I think that is a good site, and the author does know lots of stuff, but he does say some stuff that doesn't seem consistent with most other experts. As an example, he says LiFePO4 batteries are subject to "memory effects" which can be detrimental to he lifetime of the battery. Most places you find will say either LiFePO4 does not have any memory effect, or that it is insignificant (or that it has an insignificant impact).

 

[Hans Kroeger]

Let's say i charge with 0.5C. according to that chart i can charge even above 3.65V and i am still not overcharging the cell (still in the green). Can this be right?

No, there is much more to consider when charging LFP cells. Cell chemistry requires to stay within a certain envelope with your charging parameters (current, voltage, temperature) in order not to put your cell under stress. Therefore the manufacturer of the cell defines certain limits to be taken into account. Technically you may charge your cell with 0.5 C up to 3.7 Volts without overcharging it. But this will reduce the lifetime of your cells below what the manufacturer has specified for the maximum allowed cell voltage of 3.65 V.

What is the voltage at 0.5C at which the cell is overcharged? Overcharging means charging a cell beyond its designed capacity right!? So why does the voltage (pressure) rise? Since voltage and capacity are not linear it can't be only because the cell gets closer and closer to full capacity or?

It is important to understand how Amps and Volts play together during charging with the CC / CV charger. When you turn on a charger, it starts in its CC mode. It pushes a certain amount of Amps into the battery and keeps this current constant. It is only the battery which defines the actual voltage based on the growing charge it stores. The battery voltage starts to increase. The charger stays in CC mode until the battery voltage reaches the preprogrammed end of charge voltage of the charger. Once the end of charge voltage is reached, the charger switches from its CC mode to its CV mode. Now the charger keeps the voltage constant. Now it is the battery which defines the actual current based on the growing charge it stores.
Finally, the concerned curve above tells you at which point in time the battery is 100 % charged, and at which current the charger must be turned off in order not to overcharge the battery. Without such a curve you wouldn't know when to stop charging. There is nothing to tell you when your battery is full. Reaching 3.65 V is no indication of a 100% SOC.
Neither is 2.5 Volts an indication for an empty battery, as someone stated above. In many cases it does not help to oversimplify matters because it cam lead to wrong conclusions.
Battery chemistry is not a mystery but it is very complicated.

 

[Hans Kroeger]

When you didn't answer I used Google to find it. It was the (somewhat) famous Nordkyn Design site. I think that is a good site, and the author does know lots of stuff, but he does say some stuff that doesn't seem consistent with most other experts. As an example, he says LiFePO4 batteries are subject to "memory effects" which can be detrimental to he lifetime of the battery. Most places you find will say either LiFePO4 does not have any memory effect, or that it is insignificant (or that it has an insignificant impact).

He is correct, LFP cells have a memory effect. But this is quite different from what we know about batteries which must be discharged in order to accept another full charge. As you say, the impact is insignificant.

 

[Horsefly]

No, there is much more to consider when charging LFP cells. Cell chemistry requires to stay within a certain envelope with your charging parameters (current, voltage, temperature) in order not to put your cell under stress. Therefore the manufacturer of the cell defines certain limits to be taken into account. Technically you may charge your cell with 0.5 C up to 3.7 Volts without overcharging it. But this will reduce the lifetime of your cells below what the manufacturer has specified for the maximum allowed cell voltage of 3.65 V.

It is important to understand how Amps and Volts play together during charging with the CC / CV charger. When you turn on a charger, it starts in its CC mode. It pushes a certain amount of Amps into the battery and keeps this current constant. It is only the battery which defines the actual voltage based on the growing charge it stores. The battery voltage starts to increase. The charger stays in CC mode until the battery voltage reaches the preprogrammed end of charge voltage of the charger. Once the end of charge voltage is reached, the charger switches from its CC mode to its CV mode. Now the charger keeps the voltage constant. Now it is the battery which defines the actual current based on the growing charge it stores.
Finally, the concerned curve above tells you at which point in time the battery is 100 % charged, and at which current the charger must be turned off in order not to overcharge the battery. Without such a curve you wouldn't know when to stop charging. There is nothing to tell you when your battery is full. Reaching 3.65 V is no indication of a 100% SOC.
Neither is 2.5 Volts an indication for an empty battery, as someone stated above. In many cases it does not help to oversimplify matters because it cam lead to wrong conclusions.
Battery chemistry is not a mystery but it is very complicated.

Actually, if you read the Nordkyn article he spends time talking about this maximum termination current, but he admits that if you terminate at any of the shown voltages at 0.05C the only impact is that the cell will not be at 100% SoC, and he then admits that most people believe not getting to 100% SoC is a good thing anyway.

Terminating the charge at a higher residual current simply equates to stopping the charge short of 100% SOC; this is commonly done as well as it is perceived to be easier on the cells, but the effective difference only amount to a few minutes of charging in most cases and a tiny fraction of capacity only. Lithium batteries just charge too easily.

To me that part of his article is a bit of a waste.

 

[Vi s]

No, there is much more to consider when charging LFP cells. Cell chemistry requires to stay within a certain envelope with your charging parameters (current, voltage, temperature) in order not to put your cell under stress. Therefore the manufacturer of the cell defines certain limits to be taken into account. Technically you may charge your cell with 0.5 C up to 3.7 Volts without overcharging it. But this will reduce the lifetime of your cells below what the manufacturer has specified for the maximum allowed cell voltage of 3.65 V.

It is important to understand how Amps and Volts play together during charging with the CC / CV charger. When you turn on a charger, it starts in its CC mode. It pushes a certain amount of Amps into the battery and keeps this current constant. It is only the battery which defines the actual voltage based on the growing charge it stores. The battery voltage starts to increase. The charger stays in CC mode until the battery voltage reaches the preprogrammed end of charge voltage of the charger. Once the end of charge voltage is reached, the charger switches from its CC mode to its CV mode. Now the charger keeps the voltage constant. Now it is the battery which defines the actual current based on the growing charge it stores.
Finally, the concerned curve above tells you at which point in time the battery is 100 % charged, and at which current the charger must be turned off in order not to overcharge the battery. Without such a curve you wouldn't know when to stop charging. There is nothing to tell you when your battery is full. Reaching 3.65 V is no indication of a 100% SOC.
Neither is 2.5 Volts an indication for an empty battery, as someone stated above. In many cases it does not help to oversimplify matters because it cam lead to wrong conclusions.
Battery chemistry is not a mystery but it is very complicated.

Many thanks Hans for taking your time to explain it to a novice like me, learning a lot!
Really trying to wrap my head around this complicated chemistry, like why does voltage rise so steep in the beginning and end and why is it so flat in the middle at CC?? Certainly there are other factors than current and temperature at play i don't know of yet. Maybe i find one day an understandable comparison or model how this all works. With the common comparison/model to water pressure (voltage) and volume (current) i can't really make sense to it yet. Anyhow interesting subject!

 

[Ellcon123]

All batteries are complicated chemistries and they have different voltages and operating curves. LiFePo4 just happens to have a very flat curve which most are not used to. Great, as the voltage is stable across most of the capacity but also makes it difficult to know what the actual capacity is. The head and tail of the curves are very distinctive so this is where you need to be to accurately assess state of charge.

 

[Vi s]

Actually, if you read the Nordkyn article he spends time talking about this maximum termination current, but he admits that if you terminate at any of the shown voltages at 0.05C the only impact is that the cell will not be at 100% SoC, and he then admits that most people believe not getting to 100% SoC is a good thing anyway.



To me that part of his article is a bit of a waste.

Many thanks for sharing the source of this chart!
Very interesting information + nicely written in an easy to follow manner!

 

[Hans Kroeger]

Many thanks Hans for taking your time to explain it to a novice like me, learning a lot!
Really trying to wrap my head around this complicated chemistry, like why does voltage rise so steep in the beginning and end and why is it so flat in the middle at CC?? Certainly there are other factors than current and temperature at play i don't know of yet. Maybe i find one day an understandable comparison or model how this all works. With the common comparison/model to water pressure (voltage) and volume (current) i can't really make sense to it yet. Anyhow interesting subject!

Max,
I know, it is difficult to understand how the battery behaves (voltage, current, charge) when being connected to a CC/CV charger. In particularr one must understand that such a charger operates with two controlloops, one to keep the output current constant and one to keep the output voltage constant. When in CC mode the controller reads the actual current and compares it with its reference value. In case the current tends to go below the reference, the charger increases the output power a bit in order to keep the current constant.
The current transports charge (coulomb) into the battery which stores this charge. The amount of charge being stored in the battery will grow. As a consequence the battery voltage will grow too, very slow in the flat part of its charge curve, and faster towards the end of this curve. The growing battery voltage is recognized by the CC control loop which reacts by increasing the output power to keep the current constant.
As soon as the charger detects that the battery voltage reaches the preprogrammed "end of charge voltage" (absorption voltage) it turns off the CC mode and switches over to the CV mode. From here on, the controller will keep the voltage constant. The battery is nearly full and reduces the current being drawn from the charger. If the CV control loop detects a tendency of the voltage to go up, it will reduce its output power in order to keep the voltage constant. Thus the charger output current tapers off, fast at the beginning, mor slow over time.
The red line in the concerned chart tells you for a given absorption voltage, at which value of the current the battery is considered to be 100% charged and the current (charger) should be turned off.
I hope this explains a bit of the ongoing during the charging process.
Regards Hans

 

[Vi s]

Max,
I know, it is difficult to understand how the battery behaves (voltage, current, charge) when being connected to a CC/CV charger. In particularr one must understand that such a charger operates with two controlloops, one to keep the output current constant and one to keep the output voltage constant. When in CC mode the controller reads the actual current and compares it with its reference value. In case the current tends to go below the reference, the charger increases the output power a bit in order to keep the current constant.
The current transports charge (coulomb) into the battery which stores this charge. The amount of charge being stored in the battery will grow. As a consequence the battery voltage will grow too, very slow in the flat part of its charge curve, and faster towards the end of this curve. The growing battery voltage is recognized by the CC control loop which reacts by increasing the output power to keep the current constant.
As soon as the charger detects that the battery voltage reaches the preprogrammed "end of charge voltage" (absorption voltage) it turns off the CC mode and switches over to the CV mode. From here on, the controller will keep the voltage constant. The battery is nearly full and reduces the current being drawn from the charger. If the CV control loop detects a tendency of the voltage to go up, it will reduce its output power in order to keep the voltage constant. Thus the charger output current tapers off, fast at the beginning, mor slow over time.
The red line in the concerned chart tells you for a given absorption voltage, at which value of the current the battery is considered to be 100% charged and the current (charger) should be turned off.
I hope this explains a bit of the ongoing during the charging process.
Regards Hans

Nice explaination, thank you very much Hans!
That is now clear to me.

In case you know it already at it is easy for you to explain, could you kindly explain me why at the same constant current/ constant charge/ constant flow of coloumb into the battery, does voltage not also grow/rise constant/ the same/ linear to the state of charge? Why is voltage much slower rising in the middle part of the charging curve?

I have watched all kinds of presentations, lectures as well read papers concerning lifepo4 batteries like for example SOC estimation methods of lifepo4 batteries etc but i have yet to come across an explaination concerning the nonlinear behavior of voltage.

Kind regards

 

[Vi s]

Hi Max, I am 100% with you!
Taking into account that a high charging current has a strong impact on the SOC over Voltage curve, makes it even more difficult to select a fixed voltage level for turning on or off a smart active balancer.......but as always, we must live with compromises. I believe your proposed voltage level for the On/Off control is a good compromise.
Would be great if Hankzor modifies the balancer following your proposal. Would be a big improvement compared to the actual design.

Can you ask Hankzor to think about a "next generation" smart active balancer which is monitoring the total voltage of the 4 cells in order to switch on at 13.5 V, and switch off at 13.3 V, with an accuracy of 0.1 V or better.

Regards Hans

Nami replied and said following:

"We need to consider the cost and customer needs, and then change and customize the product. It will take some time to understand the market. Thank you"

Btw have a look at this one https://a.aliexpress.com/_mrbqszs

It measures total battery voltage but the threshold is 13V!

 

[Hans Kroeger]

Nice explaination, thank you very much Hans!
That is now clear to me.

In case you know it already at it is easy for you to explain, could you kindly explain me why at the same constant current/ constant charge/ constant flow of coloumb into the battery, does voltage not also grow/rise constant/ the same/ linear to the state of charge? Why is voltage much slower rising in the middle part of the charging curve?

I have watched all kinds of presentations, lectures as well read papers concerning lifepo4 batteries like for example SOC estimation methods of lifepo4 batteries etc but i have yet to come across an explaination concerning the nonlinear behavior of voltage.

Kind regards

I wish I could give you an answer, Max, but I can't. I didn't even try to understand why the cell behaves like that. I was happy to understand how the cell behaves. In case I run across some paper which answers the why, I will let you know.
Cheers Hans

 

[Vi s]

I wish I could give you an answer, Max, but I can't. I didn't even try to understand why the cell behaves like that. I was happy to understand how the cell behaves. In case I run across some paper which answers the why, I will let you know.
Cheers Hans

Much appreciated!

 

[Vi s]

Nami replied and said following:

"We need to consider the cost and customer needs, and then change and customize the product. It will take some time to understand the market. Thank you"

Btw have a look at this one https://a.aliexpress.com/_mrbqszs
View attachment 99332
It measures total battery voltage but the threshold is 13V!

Advantage, this new balancer doesn't do bottom balancing. It measures total battery voltage. Although not perfect it seems at least better than the ones we have.

 

[Hans Kroeger]

Btw have a look at this one https://a.aliexpress.com/_mrbqszs
View attachment 99332
It measures total battery voltage but the threshold is 13V!

I thought about ordering one for testing. Unfortunately it is not sold to Germany

 

[Vi s]

I thought about ordering one for testing. Unfortunately it is not sold to Germany View attachment 99340

Does this happen often? Thought AliExpress ships worldwide.

9.04US $ 10% OFF|4s 5a Lithium Battery Active Balance Board Capacitive Batteries Energy Transfer Balancer For Bms Li-ion Lifepo4 3.2v 3.7v Cell - Power Tool Accessories - AliExpress

Smarter Shopping, Better Living! Aliexpress.com

a.aliexpress.com

8.99US $ 10% OFF|4s 5a Lithium Battery Active Balance Board Capacitive Batteries Energy Transfer Balancer For Bms Li-ion Lifepo4 3.2v 3.7v Cell - Power Tool Accessories - AliExpress

Smarter Shopping, Better Living! Aliexpress.com

a.aliexpress.com

Maybe those work. You may also talk to the shop, maybe they can do something about that.

 

[Hans Kroeger]

Does this happen often? Thought AliExpress ships worldwide.

9.04US $ 10% OFF|4s 5a Lithium Battery Active Balance Board Capacitive Batteries Energy Transfer Balancer For Bms Li-ion Lifepo4 3.2v 3.7v Cell - Power Tool Accessories - AliExpress

Smarter Shopping, Better Living! Aliexpress.com

a.aliexpress.com

8.99US $ 10% OFF|4s 5a Lithium Battery Active Balance Board Capacitive Batteries Energy Transfer Balancer For Bms Li-ion Lifepo4 3.2v 3.7v Cell - Power Tool Accessories - AliExpress

Smarter Shopping, Better Living! Aliexpress.com

a.aliexpress.com

Maybe those work. You may also talk to the shop, maybe they can do something about that.

This happened the first time with Aliexpress, and I buy lots of equipment there. The other two ads also give a statement about not shipping to Germany.

 

[Vi s]

This happened the first time with Aliexpress, and I buy lots of equipment there. The other two ads also give a statement about not shipping to Germany.

As a matter of fact i know all three are the same shop. I ever asked them. Btw i purchased my new small BMS from them, they were a bit slow with responding and shipping but in the end all went well (i even got the 30A version instead of the 20A i ordered, they just said "we sent you the 30A version"), they are legit. You may chat with them, they might be not aware of that block.