Most solar installers want to sell a grid tied system, because that is what they are trained / equipped to do.
A pure DC system for air conditioning will still need to have at least some level of battery pack to be stable, perhaps 3 - 4 hours worth of run time.
The nice thing is that it does not need an inverter to power it the air conditioning compressor and that can be a significant size unit. Most problems in solar systems are going to come from the inverter and grid tie aspect. I have no interest in feeding the grid, so for me that means nothing.
If you install solar panels that can be charging up the battery pack and feeding it from early morning to very late afternoon, then it can work out in a place like AZ.
If you do need to supplement, you can always just use a AC - DC charger to keep the batter pack charged up, or buy a DC generator.
In a place like AZ, if you can take even 75% of the air conditioning load off grid, then this is at least half of your load. Even better, it takes it off during peak demand billing periods.