Just because I always try to err on the side of caution, I'd suggest that you ask your avionics guy about the voltage you plan to introduce into the system and ask about the max avionics voltage.
Keep in mind that I haven't touched an aircraft electrical system since 2005 so plenty of stuff has probably changed.
An aircraft 28-volt system utilized a 24-volt battery while the alternator's output is in the 28.2-28.8 volts range.
Same applies to 14-volt systems in aircraft. The starter battery is a 12-volt battery with a charging voltage of 13.8-14.4 volts.
If the avionics guy says you're good to go, cool.
Radio stacks were expensive back when I was flying. I'd probably croak if I knew how much a stack is now.