First, make sure your power supply is disconnected from the cells. Then using your meter, adjust the voltage on the power supply (not over 3.65 volts) and set the current to max. Then you can connect to the cells, and be confident you won't overcharge your cells. If you have good quality leads to connect to the cells with, your power supply should show max amps and the current cell voltage (
don't adjust the voltage).
The resources section has an excellent tutorial, I highly recommend you read it and follow it, it answers 99% of your questions.
To get the paper, click on the orange at the top of this page. This is a tutorial with detailed steps on how I top-balance my LiFePO4 Cells using a low-cost benchtop power supply. To get the tutorial, click on the orange "Download" button...
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