D
DURATION AT TARGET VOLTAGE (Over-Absorbing):
One area folks often misconstrue is thinking a lower charge voltage means it’s 100% safe for the LFP battery. It may not be. If your charge sources are not suitable they can still potentially over-charge by holding the constant-voltage stage (absorption) for too long. Over absorbing, even at pack voltages as low as 13.68V, can result in charging to 100% SOC. Continuing to charge beyond the point where the Li-Ions have stopped moving, from the cathode to the anode, would be considered charging more than is necessary. Charging at high voltages, beyond when the bank is full, can lead to a phenomenon known as lithium plating. If the CV (constant voltage) stage of the charger is held long enough an LFP cell can be fully charged at voltages as low as 3.42VPC.
Most lead acid designed charge sources can hold the absorption voltage stage more than long enough to cause long term damage or eat into some cycle life capacity of your expensive LFP cells. Some LFP manufacturers are now starting to understand this point, when selling into a lead-acid charger environment, and have reduced recommended max charging voltages accordingly, though some others have not. The quality of the cells used inside the battery also play a role as to how well they deal with constant voltage being held longer than is necessary.
I recently had four prismatic cells in the shop, sent to me by a gentleman who assumed a GEL setting on his charger was safe. He decided this based on Winston’s voltage specifications. He assumed, seeing as it was only 14.2V or 3.55VPC, and well within the spec, that 14.2V was safe for a nominal 12V bank. However, as I mentioned earlier, voltage is not the only factor to consider. You have voltage, duration at target voltage, and charge rate to also consider.
LiFePO4 cells are optimally charged to 100% SOC, then charging is terminated, stopped or dropped to a voltage level that will not cause major harm. This was the original design of the chemistry. This does not happen with far too many lead-acid designed chargers so you as an owner will need to chose charge sources that can be carefully programmed..
The problem the GEL setting installation was the absorption DURATION, not the voltage. At 14.2V the absorption duration was 4 hours long with no way to change the length of the absorption cycle-timer. On top of a 4 hour absorption the chargers charge rate, which was very low in comparison to the banks Ah capacity, his cells were actually hitting 100% SOC before the voltage even got to 14.2V. Continuing to charge beyond the 100% SOC point can lead to lithium plating.
In other words he was technically over-charging his bank before he even got to 14.2V because charge rate also plays a role. Once his bank hit 14.2V the charger then continued to charge them for four more hours each time he went to 100% SOC. On top of all this his so called “smart charger” was actually really quite dumb and could reset the absorption timer when ever a large load kicked in and momentarily dropped the sensed voltage below the re-absorb trigger. he also still had the temp compensation circuit active, something that is not good for LFP.
In just 150 +/- cycles his 180Ah cells could barely deliver 96Ah’s and they were puffed up like balloons. 2000 cycles? His expensive Winston LFP cells were severely diminished in less than 150 cycles while using the GEL setting we so often read about as being “safe” for LFP. If his charger had stopped charging when the cells actually hit 100% SOC, it would have been much better for the cells, 14.2V or even 14.6V is a safe “stop-charge” point, but instead it kept charging for 4+ hours after the bank was full. It could also, too easily, be re-triggered back into another 4-hour absorption cycle when a house load kicked on. Considering the boat spent much time at a dock, it is impossible to say how many hours they were maintained at 14.2V/3.55VPC.
Contrast the real world scenario above to a study conducted at a University using the same exact prismatic cells. They charged the cells to 4.0V then discharged to 0% then repeated this for 950 cycles. The cells survived 950 complete 100% discharge & recharge cycles. The difference here being the charging was 100% terminated/stopped when 4.00VPC was reached and the discharge current automatically turned on. This means the cells were only above 3.45VPC for a very, very brief period on each cycle and were never held continuously at 100% SOC..
The relationship between target voltage, duration at target voltage + charge current is where damage can occur.. When setting up an LFP system these three factors can’t be ignored;
Target Charge Voltage
Duration the Charge Source Maintains/Holds Target Voltage
Charge Rate
These three items go hand in hand with LFP.
Charging LFP is simple – Charge to target voltage then stop charging.
I just purchased a Renogy 100ah LiFePo4 battery and would like to know if anything new has been learned (in this community) about Renogy's LiFePo4 voltage settings because their documentation is still 'recommending' 14.4v float.
Well, what's supposed to happen is that Renogy's BMS will disconnect the charge source when it thinks it is full, so even if you do have "float" set for 14.4, it isn't actually connected and floating!
If this were a bare DIY battery, then maybe the long term float at 14.4v would be very bad. I certainly never held my bms-less batts that way for long periods.
From a manufacturer's standpoint, they have no idea what the end user is *really* going to use to charge. For instance:
A solar controller for lead-acid that has a "timed" absorb, say of only 2 hours reaching 14.4v, and then automatically dropping back to a 13.6 float. Mostly to ensure that they don't overcharge lead-acid in non-cyclic applications. That would result in a less than full charge on the LFP batt.
So to ensure that the LFP batt will actually get charged to full, and let the BMS decide when to pull the plug, to prevent an early termination of CV with "timed" solar charge controllers, they recommend having "float" at the same setting to ensure that charge continues until the bms decides it's time to disconnect.
My best theory anyway...
That company renogy, I don't trust their batteries agm line, I've ordered 6 of the 200ah, the 1st 4 arrived, it's when the second 2 arrived and I started testing I got pissed. These batteries would not even hold a charge over 12.85. ?.. I was really hoping to see 13.8 or even 14v
2 out of the 6 batteries didn't even work
Ordered on Amazon from their store