The cells internally is a really long microthin copper foil with the compound on it rolled into a tight jelly roll, then the electrolyte is added, they are then part charged & vented off & then sealed. The Electrolyte is not "right to the top" there is space for gasses etc.. hence when you shake an LFP cell you get a flushing sound and you ca squeeze then between your fingers... They are "almost" as tough as a pop can. When laying on the sides, the upper layers of the jelly roll will not be covered and exposes in the "gas area".
Yes, this makes sense. I imagine there is some wicking and capillary action going on through the electrodes(lfp and graphite), but if parts of the roll become starved of the electrolyte I can definitely see how it can cause huge problems in the end.
Now, an obvious question would be "so why manufacturers of these cells(eve for one) repeatedly say they can be used in any orientation" they also make EV car packs where these cells are flat on the short edge (BYD "blade" battery). Then, there are manufacturers like Tesla and their prismatic LFP pack for model 3 that has vents facing upward.
The answer may simply be "they haven't gotten the memo yet". Things are considered accepted knowledge until evidence mounts to the contrary. They may well be evidence that putting these cells on their side (long or short) is detrimental. It's just being collected. Probably better to err on the side of caution. It's just a huge shame I haven't known that
before I built my cellar, a building on top, planned entire layout and I've built a battery. Oh well, I guess these are the perils of DIY with cutting edge tech.
I have to research this topic a lot more.
THIS IS SIMPLIFIED - You want Hard Techie I'll give you links to the Battery University info... Stacking 16 cells (5.5kg bricks) on on top of another puts a hell of a lot of pressure (just from gravity) onto he bottom cells.
These cells a little lighter, but let's take 5.5kg. The recommended 300kg of force given for the compression fixture is on a surface of one cell, not per cm (that would crush them easily) or per sq. meter (that would be only about a half of 1psi). Let's take 15 cells on top of one. That would be 82.5kg.
So a good argument can definitely be made one should back off the fixture force by these 82kg. This means cells on top will be under recommend pressure, but I'd rather have not enough than too much. I'll be doing that tonight.
However if I back the pressure off and there is no "leaning tower of Pisa" situation I don't think crushing is causing it. Perhaps it is a factor.
Maybe it's a combination of a couple of things, a single one of each would seem not enough to cause failure?
We have seen NUMEROUS examples of this and how they end up leaking.
Can't argue with that. But I'd love to find out more. Were these packs using compression fixtures? If so, did they use springs, or screws, or something else?
Also, we're they leaking from the vents, or were corners separated etc?
Companies like Iron Edison went BANKRUPT cause of it and many more. 300 kgf per Centimeter (not per meter) is not a lot of pressure but some wizbangs can't get that (Compression topic beaten to death & revived too many times). Bottom Line: Proper Orientation is essential for safe longterm use.
Indeed it has. I'm compressing my cells with springs, but 300kg/cm is an insanely high pressure. That's about 104 tons on top of one cell. It would look like a squished empty pop can

The correct value is 300kg total.
Temp mismanagement & orientation is HARMING the cells and reducing calendar life. Sorry, it is as simple as that, I won't screw around with your money (some love to do so) and so I am blunt about it. There are just some basic facts that a few people love to "debate/argue" seemingly for fun. I personally blame lack of soap opera shows and bored people looking to entertain themselves.
Some people for sure do. No doubt it is a fact what you said about temp mismanagement. You said to keep it at about 15C. This is a safe default.
I've found this research article today. It is showing visually effects of charging/discharging at various low temperatures.
https://app.jove.com/t/57501/the-ef...ells-at-different-temperatures-on-degradation
Based on the above anyone can decide what temperature is appropriate for their pack (where does cost of heating/insulation outweight the benefits of few % less deterioration).
I am well aware of the numerous formats that a battery pack can be built into. Below is one of my most common handouts showing some choices. Would a "Block" format fit into your space ?
Not without serious redesign of everything else, but if I find more supporting info I'll have to do it. Probably not very soon, but probably in a couple of months time at most.
Can you also not use a Foam Insulation sheet (type with foil on both sides) underneath to provide a Thermal Break to prevent the concrete acting like a Cold Sink ?
Yes, this is a very good idea to insulate from concrete.
Operationally you should NOT stress your cells by operating at the low temp thresholds, get them up to at LEAST 10C if not 15C.
At the moment they are above 10C (14~16 today as we're having a heatwave, 13C seems average). I have good few months to consider this before I decide.
They used subcontractors to make wall mont packs. MANY MANY leaked, some caught fire too... with warranty claims the failures resulting in losses and bad management - all combined. GSL from China was one such contractor... Funny thing happened at their factory... They changed up and now are starting to make Wall Mount Packs with cells in an UPRIGHT position...
Is there a diagram of the old pack floating somewhere? (the one with issues).
Edit: Adding some useful links regarding cell orientation, but this topic probably deserves its own thread.
- regarding amount of free electrolyte in LFP cells:
https://iopscience.iop.org/article/10.1149/2.1151904jes/pdf The article analysed few cell types some with lots of free electrolyte (that makes that sloshing around) sound and some with barely any. In all cases all electrode components were well wetted. Not really surprising as they are very porous. But a very useful thing to know.
- regarding cell construction:
https://www.sciencedirect.com/science/article/pii/S001346862301513X discussing Tesla 3 cell showing air space on sides rather than up top - if it is not filled with electrolyte fully the jelly roll almost certainly is not fully submerged (as there is no gas space above the roll).
- influence of cell orientation of li-ion aging in big prismatic cells (not lfp, but useful)
https://www.sciencedirect.com/science/article/abs/pii/S037877532100762X (ask me for text if needed). These guys show different thermal behaviour in cells aged in diffrent orientation. Their recommendation is to have all cells in the same orientation, but they don't say which.
Last one, I promise. Not directly related to cells on their side, but "temperature and pressure gradients" in general.
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https://www.researchgate.net/public...drical_cells_revealed_by_post-mortem_analysis
Excerpt from the abstract:
The most remarkable result is that both cycled cells displayed highly uneven aging primarily of the graphite electrodes, showing large differences between the central parts of the jellyroll compared to the outer parts. The aging variations are identified as differences in capacity and impedance of the graphite electrode, associated with different SEI characteristics. Loss of cyclable lithium is mirrored by a varying degree of lithiation in the positive electrode and electrode slippage. The spatial variation in negative electrode degradation and utilization observed is most likely connected to gradients in temperature and pressure, that can give rise to current density and potential distributions within the jellyroll during cycling.