When you say:
Are you saying that all your wiring will be AC (you will have no DC circuits (beyond the inverter and charger(s))? Or are you just mentioning that your van will have AC and have a 12v DC circuits?
If its only AC circuits, it'll be pretty simple to just pick a wire size and stick to it since its so standardized and such low current.
But I think that's not what you mean. Setting aside the inverter which will require much larger wires than everything else in most cases, the way I would go about it is figure out what (A) your highest current appliance/circuit will be (B) Your longest medium current to high current circuit will be (in terms of round trip distance) calculate the proper wire size for those circuits, then size everything based on whichever is larger. Its likely 10AWG would be fine for everything but the inverter and maybe chargers, but its hard to say without knowing the specifics of your situation.
One point to keep in mind, not all wire of the same gauge is equal. Insulation temperature ratings effect how much current a wire can safely carry. Many of the charts you see assum 105*C marine wire which is higher than a lot of household wire, speaker wire, etc. So check insulation rating before you buy, or just buy a big bulk roll of 105*C marine wire (its best for mobile builds anyways).