Standard physics says, you need both terminals for the current to flow.
But you can get a shock from just one PV terminal especially if string voltage is very high (hundreds of volts if not 1kV+). How so?
Air itself does have some conductivity depending on many factors (temperature, humidity). Not a lot of current flows through, but possibly enough to feel it in some conditions.
But much more dangerously there may be moisture in the other plug that may complete the circuit to ground and that may be lethal if the other one is touched.