No. It has no clue what is connected to it beyond the numbers you program. All it sees are voltage and current. You could have 18 batteries or one, and it wouldn't know the difference.
The shunt has no idea what the state of charge is until the sync parameters are hit. The sync parameters are when the battery is fully charged. Once that is attained, the shunt sets itself to 100% and then counts the amp hours in and out continuously computing the state of charge. It will remain relatively accurate for a couple weeks but should be fully charged at least a couple times a month. More is better as that ensure the batteries are at elevated voltage long enough to do any needed cell balancing.