If they start at 100 SOC, when the 230AH battery is at 20% SoC (.20*230=46AH remaining), the 280 AH will have (280-(230*.80))=96 AH remaining and will be at 96/280=34% SoC. If you are running the 230AH to 0% SoC, then at that point there will be (280-230)=50AH left in the 280AH battery. So 50 AH and 50/280=17.8% of your 280 AH battery goes unused.
On edit: That's a rough estimate, but IIRC the effect is muted by the larger bank feeding the smaller bank...which throws some complexity into just how much capacity is waster/unused. IMO, just don't do it on that scale. 272 vs 280 is fine. I'm all for keeping it simple.