In a diy battery pack the pressure is held/applied by the endplates that could be fixed with a rigid rig. So the more cells the more force applied to the endplate therefore more pressure through the cells. Which is why a higher pressure is experienced by each cell as the cell gets a higher SOC in a compressed/fixed/rigid inclosure..
Or how I like to look at it. If I’m pushing on a car trying to move it (like I’m one cell trying to expand)
and my equally strong buddy (second cell trying to expand) pushes on my back, we will create more force/mass therefore more easily moving the car. Now if that car was against a concrete wall (like cells against fixed rigid end plates) then my buddy and I would simply be exerting our force against the concrete wall, which is more force than I could put on the concrete wall if I was the only pusher.. which would create a higher psi at the concrete wall..
Point is 2 cells (2 people) apply more force to the end plate (concrete wall) than one cell (one person would), which creates more pressure throughout the rig or throughout the push/SOC.
Since my buddy is pushing on my back it’s not double the force as it would be if he was pushing aside of me but it’s still more force with two of us like it would be with 1 cell against another cell, which makes more force than just one cell.
I might not have went to college but I have pushed a lot of cars..