Ok, so just for some napkin math references...
Let's say you want to start out with a 100Ah LFP battery because it's the Bee's Knees. What does that battery buy you?
A standard plug-in heater will kill the battery dead in about 45 minutes
An 8000BTU (smaller) AirCon system will last you 1.5 hours
The InstaPot will work for about 2 hours
A microwave will get you about 45 minutes of cooking
Think of Watts like Grams, they're really small and it takes a LOT to do much.
The whole 12v thing VS 24v thing really comes into play when you get up above about 2Kw of inverter to feed all the stuff. As a rule of thumb you want to keep your wires and fuses below 200a of draw, but the larger the amperage, the larger the wires and fuses need to be and that becomes $RealMoney real quick. If you power a 2Kw inverter on a 12v battery you need a 200a fuse and wire (basically, napkin mathing here for the concepts) but if you do a 24v bank, that 200a becomes 100a (because watts are Volts * Amps) which is much thinner wire and smaller fuses. Conversely, if you had a 24v battery system and was willing to pay for the 200a wire you could swing a 4Kw or 4.5Kw system which gives you Moar Powah! to do The Things.
The other factors involved are capacity (how long you can USE all The Things) and generation (how fast you can refill the batteries) which becomes a balancing act for multiple reasons like...
Space for batteries. 24 LFP batteries sounds great until you're sleeping in the drivers seat because there's no bed space left.
Space for panels. If you can only physically fit so much panel on the roof, how much can you generate?
Location. If you're boondocking in Arizona you're going to get a lot more sun than boondocking in Vermont.
Budget. Those $800 BattleBorns look cool, but don't buy you much else on a $1000 budget.
Auxiliary systems. If you need to feed 12v appliances how are you going to do that with a 24v bank?
Head over to the Resources section (or someone's handy signature link) and grab the Power Audit form. It's going to tell you 3 primary things. 1: How big does your inverter need to be. 2: How much battery bank you need to feed it for $N many days of krappy weather. 3: How much solar panel you're going to need to put up to recharge those batteries in a reasonable amount of time.
The biggest challenge I think for any RV system is physical space. Where do you stick the batteries? How much roof area do I have for panels? Where do I stick the inverter? Where do I stick the AirCon condenser and compressor and evaporator? Where do I stick the cat tree?
The nice thing about the Power Audit form is that you can play around with it all you want and just save copies. Start by just putting in the wish list of things that would be cool to have like 12k BTU AirCon for 24 hours and the 5000w stereo system and the MargaritaMaster-9000 and the 65" TV with satellite internet. It's all just blanks on a form, you can't break anything. Then throw in how much solar panel you think you can mount and how much battery capacity you think you can stuff under the floor boards and the couch and such. Then start whittling away until everything meets in the middle.
There WILL be a point where what you NEED and what you can ACTUALLY DO will overlap and THAT will be YOUR system. It won't be a perfect system for me, or a perfect system for Supervstech, but it'll be perfect for YOU and that's the goal.
If you're really wanting AirCon for any length of time I highly recommend starting out with a 24v system so you can have the larger inverter that is going to power the Aircon. I also highly recommend going with LFP because you just can't beat the storage density. Grab a tape measure and some graph paper and start doodling out what you've got to work with for space.
I know, it sounds like a royal PITA to do all the number crunching, but it's cheaper than spending thousands of dollars on stuff to find out you can't use (Learn from my spare parts bin!) it and just missed your return window. Once you've got a rough plan of what kind of parts you'll need, run it past us to figure out what you missed. Don't worry, we ALL miss Something our first couple of tries.