PV arrays are commonly strung to 400-500 volts instead of the common per panel voltage of 50 volts. This is because PV wires are long and the cost for heavy gauge wire would be excessive. This is the same issue with batteries, we just accept it due to short cables. But it sure would be nice in some cases to put the batteries somewhere else than the inverter and that's just not feasible at 48 volts.
EVs are operating 400 to 800 volts even though the wiring would be very short. It doesn't take much to make higher voltage a winning idea.
We already have to deal with lots of voltages above 60 volts. Grid, load, PV. A 450 V PV array is a serious safety issue. If we can handle that, then the battery would be similar.
In some ways, having exposed 48V battery wiring engenders a certain comfort with exposed conductors that is not all that safe even at those low voltages (witness Will arcing his Ruixu stack). If everything was actually insulated and treated as high voltage, that might lead to a more uniform treatment. For example, someone inside an inverter touches what they think is a battery lug and it is AC. If everything is dangerous, then there isn't this "safe" over here, "unsafe" over there division that can get confusing to some.
High voltage makes things more efficient inside the inverter, too. Capacitors would be smaller, conductors smaller, MOSFETs smaller, etc. This applies to the AC inverter, but also to the PV to battery circuits, a smaller voltage change.
I'd skip 100 volts and go to 200 volts, 64s cells. That is 1/4 the amps in the wire. For the same losses, the wire can be 16 times smaller. You could wire this with ordinary house wiring like you use for AC.
192 V is a thing for solar, so not entirely new territory:
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Mike C.