Hello, my cells are new and have not done a deeper discharge yet, the attached image is the deepest discharge I have done. I however I noticed a significant voltage difference between cell 8 and 7, I have an active balancer connected as well and it turns on the red light on cell 7-8 but the voltage difference doesn't seem to be reducing.
I confirm everything is fine connection wise so what else should i be looking at?
The balancer leds turns on when cell voltage differences are >0.2V. This should not happen between 3V and 3.5V cell voltages on equal and balanced cells.
The balancing current of such balancer is usually lower than 1A. This may be enough for new and equal cells with small capacity differences but usually not for capacity deviations of more than 10Ah. (depends on the cycle use)
To get a quick idea of the equal cell capacity, you can discharge them all to exactly the same voltage, well below the normal working voltage (3 - 3.3V). 2.8V is safe and reliable. Don't go lower than 2.6V.
Discharge all cells by using them normally. When one single cell reaches 2.8V, disconnect your load.
Discharge every other cell individually to exactly the same voltage (2.8V).
You can use an electronic load or simply a 0.3 - 1 ohm power resistor of +-50W with a cooler while monitoring the cell voltage with a decent multimeter.
The resistor may get very hot, put it on a safe place and don't forget it...
After discharging, let the cells rest 15 minutes and measure/discharge more until you get the same voltage.
When all cells are at 2.8V, charge the set again (in series) with max 15A and measure the cell voltages from time to time.
When one cell gets above 3.35V, measure them all frequently. They should rise all equally up to 3.5V.
Between 3.35V and 3.5V, the cell voltage differences should not be more than 0.1V and the leds of your balancer must stay off.
If not, your cells may not have equal capacity which is problematic.
This test says nothing about the cell capacity, only about cell capacity differences.
End of life cells may all have +- the same reduced capacity and can still be used 'normally' for short time.
Capacity differences are really problematic, will only come worse and may lead to severe total capacity loss.
BLS selects recycled cells on remaining capacity and tries to make a matching set (which is never exact for old cells).
How more cells are used, how more difficult to get a matching set. That's why people with 4 cells have less issues than people with 8-16 cells.