So if you have 2 solar arrays feeding 2-8kW AIO's SCC's (Solar charge controllers likely with MPPT). They can be wired to one battery bank. The outputs of them if combined in parallel (they must be able to be paralleled) would give you 16kW single phase output to a distribution panel. The AC voltage stays the same in parallel just like it does in batteries but the capacity adds. Or if you stack them the AC output will give you 2 phases (L1 and L2 hots) (split phase ) set 180 degrees apart for double the voltage. 3 phase the outputs are 120 degrees apart. (L1, L2, L3 hots).
Say you need to power a distribution panel that feeds loads that need only 120vAC* or 1 hot leg with 16kW capacity. Thus the higher capacity of 2 AIO's in parallel might be a choice. However if you have a mix of loads that are 120vAC and 240vAC. A stacked arrangement of the 2- AIOs will give you two hot legs of 8kW.
Going to 3 phase is worth it if you run 3 phase equipment.
* If you live in a country that has 230vAC single phase standard you would likely never stack for split phase.