The reason why they make batteries of differing voltages is not for the application, it's for the weight. As you up the amphour capacity of the battery, it simply gets heavier and heavier, more than an full-sized adult could lift. Reducing the voltage is a strategy to increase the amphour capacity by decreasing the voltage, for the same size battery. It's then expected that you wire them in series to get the correct voltage. That's why you see big batteries with voltages as low as 2V. You'd need 6 of those in series to charge at 12V.