There's was to mitigate some of this right? I believe you're an electrician. There's protective gear I see them wearing on youtube for arc flash...like face shields and gloves. But, to your point is exactly why I wanted a battery professionally made where It's plug and play not a diy one. Just plug the battery in via a Anderson pole or something. But also, we're playing with 500-600 VDC from the solar panels into the charge controllers right? Isn't this similar.
Difference is current, as Tim said. PV is still plenty of current for shock hazard, and will pull a long flame.
Battery will dump massive amount of energy, splatter metal. One guy had a fault in his LiFePO4 golf cart. Didn't even blow fuse, but splattered a poorly connected busbar. At 600V vs. 48V I think true arc-blast shock wave more possible with 600kW ~ 6MW or so delivered. 600V x 10,000A x 0.01 seconds = 60kJ, similar to an entire carton of ammo.
Just having the series connected batteries isolated by pull-out connectors (Anderson), while current flow stopped, would make them safe to work on. Just like 600V or 1000V PV strings with MC connectors.
(Those guys who say they cut off MC4 connectors and solder or crimp splices - what is their practice for electrical safety while making such splices??)
BYD sells batteries that are part of UL listed ESS for Sunny Boy Storage. Two to four boxes of cells stack on top of each other, connecting in series.
I'm still dreaming of DIY HV battery (maybe REC BMS), or series connected server rack batteries (would likely require occasional balancing, possibly 48V charger which could be AC or PV powered, relays or just pluggable connectors.)