Building my first system, and I think you'll have trouble finding an MC4 connector for 6 Gauge. Most are made for 10 gauge with a few for 8 Gauge.
I consider that a design limitation, or a speed limit. What I did with my 6 panels, 100 watts each, I set them up 3 in series, with 2 sets of these in parallel (3S2P). When I went from 12 VDC to 36 VDC, it really reduced the size of the wire I needed for my voltage calculator. Each string of solar panels will be 10 gauge wire fed into a combiner that has an 6 Gauge run to the charge controller. This 6 gauge is another one of the design limitations I had because that's the largest wire that would go in my charge controller. With 6 Gauge wire and 600 watts of panels, I found I could only place the combiner 10 to 15 feet away from the battery before loss kicked in. The 6 Gauge wire is bare wire into the charge controller and terminal block for me, so no connector needed.
I think for higher rating, its different connectors, unfortunately, I don't know what those connectors are. Andersons are a common connector, and I have 50 amp Anderson connectors for a small portable panel to hook to a charge controller. The Anderson plugs come in higher Amperges. One drawback to the Anderson connectors is they are not nearly as waterproof as an MC4 connector. MC4 has an IP67 rating, which means it can be rained on and sprayed with a jet of water, but once you see the Anderson plugs, you'll see they are more exposed to the elements.
A few weeks ago, I found some MC5 and MC6 connectors, but these had no technical descriptions and as far as I know it was a vendor mislabeling an MC4 connector.