Was watching a video Ian of Watts247 had put out and you can set one LV6548 to 208V, the wild leg for 3 phase.
Buying 5 LV6548's wouldn't be cheap. I think you might get by with 3, run off PV and battery. If you want grid charging capability, buy a AC to DC charger (although larger ones aren't cheap either). I don't know if what you propose would work, it might. Just remember the overhead per LV6548 is around 60 to 65W at idle, so 5 units x 60 is 300w x 24 hours would be 7200w you need to generate just to keep the units running in an idle capacity. You could turn some off such as the 3 to generate 3 phase power when you don't need it.
Personally, I'd try it with just 3 units as you will probably want 3 phase power off grid eventually to be permanent.