@Carlos_Sol-Ark has set it to 99% to try that.If you set your TOU setpoints to 95% as suggested by @Brucey then pv will only charge to that before pushing the rest to grid. Think of the TOU setpoint as the "discharge to...." setpoint. The Sol-Ark will even "sell" out of the batteries down to the TOU setpoint.
In other words, "battery first" will come into play until the batteries get up to the TOU setpoint, then PV gets pushed to AC until TOU calls for a higher