kWh is a unit of energy, while kW is a unit of power. A battery bank stores energy and is rated in kWh. A solar panel delivers power and is rated in kW. If you run a (hypothetical, and in ideal circumstances) 1000W (1kW) solar panel for one hour, you have generated 1kWh of energy.
So now you can start calculating how much energy you use, and how fast you need it replenished in your battery - and when during the year is your worst solar generation. Those factors will determine your battery size and solar panel needs.