I'll be the dissenting voice. I like 2P pairing and have had great luck with my 2P4S battery.
With a 2P16S setup, you have the opportunity (aka a bunch of work) to create equal pairs of cells based on capacities.
So if you have 32 cells of varying capacities, you can make equivalent pairs by pairing the highest capacity with the lowest capacity, second highest capacity with second lowest...
With 2x 16S batteries, you'd be better off putting your highest 16 cells in one battery and your lowest 16 cells in the other battery.
Do you have any idea what your 32 cells' capacities are?
To answer your question (finally! sorry!), BMSs have a limited amount of balance current. If you double up cells in a 2P configuration, theoretically it would take double the current to balance the cells.
Conversely, if you created equal pairs of cells, you would have less need to balance.