There's a voltage drop calculator in my signature. Use it to determine the wire size you need. At first glance, it serms like 2/0 is overkill for your MPPT-battery connection. Note that length means the total length of the circuit round trip (bat pos to load pos, load neg to bat neg). So for instance, if battery is 10 ft from inverter, round trip is 20 ft.
The load negative needs to be connected to the other battery negative post in order to keep the bank balanced. Otherwise you'll draw and charge more from the first 24V battery in that parallel bank.
Search the forum for ways to wire parallel batteries. There are multiple examples. What I describe is the "diagonal" approach.