OK, a couple of things to start out with. Glad you want a 24V system, because I already have in place what I think you are talking about. I have this 24V inverter for my workshop, which has a built in AC to DC charger, and a transfer switch for grid connection.
Free Shipping! Schneider Electric Conext SW4024-120/240 Inverter/Charger, 4000W, 120/240VAC, 50/60Hz, 30A Transfer, 24VDC, 90A Charger, RNW8654024
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When you say you want "4000 watt capacity", are you saying you want 4000Wh of power, because obviously a 3000W inverter can't provide you with 4000W.
Panels are the single cheapest component these days, so please don't say you can only afford two 200W panels. Most likely, you can't afford more than 400W of RETAIL panels. Instead shop on Craigslist, with local pickup. My last purchase was just last year, and I got 245W panels for 55$each. I ended up buying both for myself and also for several neighbors. Cash and carry. Shipping is baked into the price of new panels that get mailed to you, so don't do that.
Why do you want two 40A charge controllers? Why not one 80A. BTW, with only 400W of solar that works out to be 400W/25Vcharging = 16A. Assuming you only get 85%, that's ~14A. If laying flat on the roof of the RV, then expect only 75%, or 12A. So, even with 800W of panels you'd only be pushing 32A max, and more likely 24A in the real-world.
Where is your battery compartment? Is it external and exposed to the weather, or inside the RV. IF Li batteries are charged when below freezing, they'll get destroyed. If you have 200Ah at 24V and you want to charge at 1/4C you'd need 200Ah X 0.25C X 25V X 1.33fudgefactor = 1662W of panels, more than double what your eventual plan is. Remember, laying flat, any panel will never make anything close to their rated power output.