This is not possible - the 6000XP only supports 240v split phase (3 phase support also on its way with a future firmware update and multiple 6000XP's). There's no way from my understanding to combine the 2 hots into a single 6000 watt 120v leg... What you can do is parallel 2 6000XP's to get 2 6000 watt 120v legs though.
All of the HF* split phase inverters are 2 inverters per box. The control circuitry that allows them to set a 180 degree phase difference or a in phase parallel has to be there even if not available to the end user. Otherwise you could not parallel 4 inverters (2- 6000xp) together to double the split phase output.The 6000xp is a 120/240 split phase inverter. You can parallel another to get more Amps of 120/240v split phase. If you only use one line of the split phase, at some point you may get an unbalanced load problem. It can't output 100% power on line 1 and 0% power on line 2.
Since the manual for the 6000xp does not provide a specific setup like those for other split phase AIO's (The SRNE for example) I am willing to accept they do not want you doing it from 1 box.
*I am talking only about HF inverters. Those inverters that utilize a transformer on their AC output (LF style) are a different critter.
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