Dang, wish I’d looked into this sooner as I already have a 22 Ah Li-ion battery. Seems like there are trade-offs between the two chemistries. The lithium ion batteries are going to be lighter, the LFP batteries are going to be cheaper, but mounting the LFP‘s will be a bit of a hassle. However, to me, the most interesting benefit of the LFP batteries is it they advertise faster charging times — 2 to 3 hours versus 4 to 6 or more. I recognize that solar charging times will be driven by the output of my solar system, so no advantage there. But if I can get most of a charge on the LFP battery in 2 to 3 hours via AC, that would significantly increase my flexibility. I guess the faster charging times of the LFP batteries is due to the increased charging current they can use.
As far as range, you may be a little optimistic. Given that I’m a pretty big guy, over 200 lbs, the bike weighs 75 lbs, and I’ll probably have close to 100 lbs of gear between panniers and a trailer, plus whatever weight the LFP battery adds, I think that motor will be working pretty hard a lot of the time. But more range is more range, whether we’re talking 30 versus 60 or 50 versus 100 miles.