A way to store summer photons for winter combustion would be useful.
Biofuels are one way. Your biogas could be good. Maybe biodiesel. Firewood is basic.
But if hydrolysis and hydrogenation let spare photons boost energy content of biodiesel (not to the point of "grease car" which apparently cokes up the engine), that could add to the mix.
Alright, I'll let you in on the hydrogen thing that I know of. Back in the late 80's, there was this fella by Des Moines, IA by the name of John Lorenzen.
https://www.motherearthnews.com/renewable-energy/self-taught-engineer-zmaz80mazraw There is a Youtube video out there about him but you can't be in the USA to see it or to access you need a VPN.
Dad found his phone number and took us 3 boys on a road trip after calling him and John invited us down for a visit. We killed the whole day there. John was close to 80 years old and nuttier than a fruitcake. But he was interesting. He ran HHO generators on his vehicles, claimed he got 10 mpg more with it (carburetors back then) and he leaned it out, had a big solar collector on the roof of his shop and had machinery he handbuilt years earlier when he was farming that was ahead of it's time. He always said Minneapolis Moline stole his tractor cab idea.
He had 3 Jacobs chargers in his yard, no utility hookup. Big bank of Edison batteries. He would throw a switch that was connected to a series of stainless plates and drop that in a bucket of water. Then he'd take a torch lighter and set off the hydrogen, laughing like a crazy man the whole time. It was quite entertaining.
John always wanted to bottle the hydrogen and heat his house. He claimed he had been filling 100 lb cylinders for his cookstove for some time, took some time to get the burn just right.
He wanted to take a 1000 gallon LP tank, bury it in the yard and store hydrogen for his house furnace in it. I never was back again to see if he succeeded; and I don't recall ever seeing a bright burst of light at night coming from his direction.
First thing is hydrogen embrittlement of steel, second is how to store enough capacity. Compressed hydrogen still isn't energy dense.