Basically the whole saga is due to being too cautious! I hadn't got the plugs seated in the sockets, but for some reason thought it would be prudent to do so prior to adding the B+ cable, saw the spark & then went down a rabbit hole.I don't get how you're seeing this, the plug shouldn't be plugged in to your BMS at all until it's wired to the battery complete.
B+ and 16th Cell wires are wired together, you shouldn't have them separated at all they should go to the same connection point and same fuse.
Probably the over-cautious approach is due to the concern of not wanting to vaporize a lot of very nice kit.
Many thanks for your help!