The difference between a sub panel and a main panel can be seen in the neutral and ground wires.
Main panels tie all neutral and grounds together and then bond that grouping to an earth ground rod.
Sub panels must keep neutral and ground wires separate and run them back to the main panel separately.
If your off-grid system is somehow tied back to your main panel, then its a sub panel. But if its a stand alone system with no electrical connection to the main panel, then it could be referred to as a 2nd main panel.